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The Rayleigh-Jeans Radiation Law and its Derivation |
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The Rayleigh-Jeans Radiation Law was a useful but not completely successful attempt at establishing the functional form of the spectra of thermal radiation. The energy density u_{ν} per unit frequency interval at a frequency ν is, according to the The Rayleigh-Jeans Radiation,
where k is Boltzmann's constant, T is the absolute temperature of the radiating body and c is the speed of light in a vacuum.
This formula fits the empirical meansurements for low frequencies but fails increasingly for higher frequencies. The failure of the formula to match the new data was called the ultravioletl catastrophe. The significance of this inadequate so-called law is that it provides an asymptotic condition which other proposed formulas, such as Planck's, need to satisfy. It gives a value to an otherwise arbitrary constant in Planck's thermal radiation formula.
Consider a cube of edge length L in which radiation is being reflected and re-reflected off its walls. Standing waves occur for radiation of a wavelength λ only if an integral number of half-wave cycles fit into an interval in the cube. For radiation parallel to an edge of the cube this requires
Between two end points there can be two standing waves, one for each polarization. In the following the matter of polarization will be ignored until the end of the analysis and there the number of waves will be doubled to take into account the matter of polarization.
Since the frequency ν is equal to c/λ, where c is the speed of light
It is convenient to work with the quantity q, known as the wave number, which is defined as
In terms of the relationship for the cube,
Another convenient term is the radian frequency ω=2πν. From this it follows that q=ω/c.
If m_{X}, m_{Y} and m_{Z} denote the integers for the three different directions in the cube then the condition for a standing wave in the cube is that
Now the problem is to find the number of nonnegative combinations of (m_{X}, m_{Y}, m_{Z}) that fit between a sphere of radius R and and one of radius R+dR. First the number of combinations ignoring the nonnegativity requirement can be determined.
The volume of a spherical shell of inner radius R and outer radius R+dR is given by
If
This means that
Now the nonnegativity require for the combinations (m_{X}, m_{Y}, m_{Z}) must be taken into account. For the two dimensional case the nonnegative combinations are approximately those in one quadrant of circle. The approximation arises from the matter of the combinations on the boundaries of the nonnegative quadrant. For the three dimensional case the nonnegative combinations consistute approximately one octant of the total. Thus the number dN for the nonnegative combinations of (m_{X}, m_{Y}, m_{Z}) in this volume is equal to (1/8)dV and hence
The average kinetic energy per degree of freedom is ½kT, where k is Boltzmann's constant. For harmonic oscillators there is an equality between kinetic and potential energy so the average energy per degree of freedom is kT. This means that the average radiation energy E per unit frequency is given by
and the average energy density, u_{ν}, is given by
The previous only considered one direction of polarization for the radiation. If the two directions of polarization are taken into account a factor of 2 must be included in the above formula; i.e.,
This is the Raleigh-Jeans Law of Radiation. It holds empirically as the frequency goes to zero. To see how it plays an important part in the derivation of the Planck formula for thermal radiation see Planck formula.
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